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Q.

How is Gibbs energy (G) related to the cell emf (E) mathematically ?

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Detailed Solution

ΔrG=nFEcell o (or) ΔrG=nFE cell 
where G = Standard Gibbs free energy change
n = no. of electrons transferred
F = 96500 coloumbs
E = emf of the cell
ΔrG = Free energy change
Ecell 0 = standard electrode potential

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How is Gibbs energy (G) related to the cell emf (E) mathematically ?