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Q.

How many are disproportionation reactions?

(i) 2Cu+Cu2++Cu0

(ii) 3MnO42-+4H+2MnO4-+MnO2+2H2O

(iii) 2KMnO4ΔK2MnO4+MnO2+O2

(iv) 2MnO4-+3Mn2++2H2O5MnO2+4H+

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answer is 2.

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Detailed Solution

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The redox reaction in which one element of reactants undergo oxidation as well as reduction is called disproportion redox reactions.
3MnO42+4H+Δ2MnO4+MnO2+2H2O is called disproportion redox reaction.
(1) 2Cu+Cu+2+Cu:disproportion redox reaction
(3) 2MnO4ΔK2MnO4+MnO2+O2 this reaction is not possible because reactant (MnO4) does not exist.
(4) 2MnO4+3Mn2++2H2O5MnO2+2H+ comproportionation redox reactions.

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