Q.

How  many  complexes among  the  following  are  paramagnetic

[Mn(CN)6]3 ,  [Cr(H2O)6]3+ ,  [Co(en)3]3+ , [V(CO)6] , [Ni(NH3)6]2+ , [Ni(dmg)2]

[Pt(Cl)2(NH3)2]  , [Cu(NH3)4]2+ ,  [Cu(CN)4]3

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answer is 5.

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Detailed Solution

4FeCr2O4+16NaOH+7O28Na2CrO3+8H2O

Let  the oxidation  state  of  C in CrO42 is x.
So, x+4(-2)= -2  or x=6

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