Q.

How many dichlorocyclohexane would be produced upon free radical chlorination of chlorocyclohexane ? (including steroisomers)

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answer is 9.

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Detailed Solution

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The products formed are 

(i) 1,1 - dichloro cyclo hexane

(ii) 1,2 - dichloro cyclo hexane (3 - isomers)

(iii) 1,3 - dichloro cyclo hexane (3 - isomers)

(iv) 1,4 - di chloro cyclo hexane (2 - isomers)

total = 1+3+3+2 = 9 isomers

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