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Q.

How many following statement(s) is/are correct.
a) White phosphorous is insoluble in both water &CS2
b) Red phosphorous is soluble in water but insoluble in CS2
c) Ignition temperature of white phosphorous is more than red phosphorous that is why white phosphorous glow in dark.
d) β – black phosphorous is prepared by heating of white phosphorous at 473K.
e) α – black phosphorous is formed when red phosphorous is heated in sealed tube at 803K.
f) Red phosphorous does not react with caustic alkali.

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answer is 3.

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Detailed Solution

White p insoluble in water but Soluble in CS2

Red p insoluble in both H2O and CS2

White Phosphorus glows when exposed to oxygen or air because of combustion or oxidation of it and Ignition temperature of white phosphorous is less than red phosphorous.

Hence, d,e,f are correct

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