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Q.

How many geometrical isomers are possible in Pd2+NH2CHCH3CO22?

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a

2

b

3

c

4

d

6

answer is C.

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Detailed Solution

Geometrical Isomers in Pd2+ Complex with Amino Acid Ligands

The coordination complex Pd2+ NH2–CHCH3–COO2 involves palladium in a square planar geometry, coordinated with two bidentate amino acid ligands.

Such square planar complexes with two bidentate ligands exhibit two geometrical isomers:

  • Cis isomer: Both ligands adjacent to each other around Palladium center.
  • Trans isomer: Ligands opposite each other around Palladium center.

Therefore, the number of possible geometrical isomers is 2.

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