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Q.

How many litres of Cl2 at STP will be liberated by the oxidation of NaCl with 10 g KMnO4 in acidic medium : (Atomic weight : Mn = 55 and K = 39)

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a

3.54

b

7.08

c

1.77

d

None of these

answer is A.

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Detailed Solution

Cl+  MnO4     Mn+2  +  Cl2Change in oxidation state of 'Cl' =2Change in oxidation state of 'Mn' =5Eq  of  Cl2  =Eq  ofKMnO42mole  of  Cl2=5  10158mole  of  Cl2=502  ×  158  =  0.15823  moleVolume  of  Cl2  at   STP=0.15823  ×  22.4  =  3.54  L

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