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Q.

How many mL of 0.125M Cr3+ must be reacted with 12.00mL of 0.200M MnO4 if the redox products are Cr2O72– and Mn2+

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a

24mL

b

32mL

c

8mL

d

16mL

answer is D.

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Detailed Solution

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Cr3++MnO4-Mn2++12 Cr2O7-2   

Equivalent of Cr3+=3× moles of Cr3+

Equivalents of MnO4-​=5× moles of MnO4-

Amount of Cr3+=0.125×V millimole =0.125×V×meq

Amount of MnO4- ​=0.200×12.00×5 milliequivalent

0.125×V×3=0.200×12.00×5

V=32 mL

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