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Q.

How many next nearest neighbours are present for Zn+2  ions in FCC arrangement of  ZnS.

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answer is 12.

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Detailed Solution

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Next nearest neighbour of Zn+2  would be = no of nearest surrounded  Zn2+ ions
next nearest neighbour of  s2 would be = no of nearest  s2 ions  =12(due  to  FCC)
and their number of neighbour ratio is 1:1 and that make  Zn2+ neighbour are 12.
 

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