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Q.

How many numbers of following statements are correct? 
i) When pure αD glucopyranose is dissolved in water, its optical rotation slowly changes.
ii)  αD glucopyranose and  βD glucopyranose are anomers
iii) Methyl glucosides do not react with Fehling's or Tollen’s reagent
iv) αD glucopyranose react with NaHSO3 to form white precipitate
v) αD methyl glucoside and βD methyl glucosides are anomers
vi) Reduction of Fructose with Na-Hg /H2O gives both sorbitol and mannitol

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answer is 5.

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Detailed Solution

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Statements (i), (ii), (iii), (v) and (vi) are correct.

αD glucopyranose do not react with NaHSO3.

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