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Q.

How many of the following ethers cannot be prepared by willamson’s synthesis ?

C6H5OC2H5,C6H5OCH3,C6H5CH2OC6H5 C6H5OC6H5(CH3)3COC(CH3)3 (CH3)3COCH3

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answer is 2.

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Detailed Solution

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Williamson's synthesis required that the alkyl halide should be 1 and alkoxide ion may be 1,2 or 3 . Thus, two ethers which cannot be prepared by Williamson's synthesis are :C6H5OC6H5 and (CH3)3COC(CH3)3

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How many of the following ethers cannot be prepared by willamson’s synthesis ?C6H5OC2H5,C6H5OCH3,C6H5CH2OC6H5 C6H5OC6H5, (CH3)3C−O−C(CH3)3 (CH3)3C−O−CH3