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Q.

How many of the following give isocyanide test?

(A)Tertiary butyl amine

(B)Secondary butyl amine

(C)CH3CONH2

(D)Ph-NH2

(E)CH3-CH2 -NH -CH3

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a

2

b

1

c

3

d

4

answer is C.

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Detailed Solution

Isocyanide test is also known as carbylamine test.

It is used to test primary amines by converting it into isocyanide.

RNH2+CHCl3+3KOHΔRNC+3KCl+3H2O

Here, Tertiary butyl amine, Secondary butyl amine and Ph-NH2 are 1 degree amines so they can give carbylamine test.

Hence, option (A), (B) and (D) are correct.

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How many of the following give isocyanide test?(A)Tertiary butyl amine(B)Secondary butyl amine(C)CH3CONH2(D)Ph-NH2(E)CH3-CH2 -NH -CH3