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Q.

How many of the following hydrides are electron deficient?
i)SiH4             ii) AlH3                   iii)  B2H6           iv)  GaH3

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answer is 3.

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Detailed Solution

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Boron has 3 electrons in the valence shell and it requires 5 electrons to complete its octet.
From the structure we can see that diborane has a 3c-2e bond, hence it is electron deficient.

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Aluminium has 3 electrons in the valence shell and it requires 5 electrons to complete its octet , if it forms a bond with 3 hydrogen it still requires more electrons to complete its octet. Hence it is electron deficient.

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Silicon has 4 electrons in its valence shells and requires 4 electrons to complete its octet and here it forms a bond with 4 hydrogen atoms hence SiH4 is an electron precise molecule.

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Gallium has 3 valence electrons and it requires 5 electrons to complete its octet, if it forms a bond with 3 hydrogen it still requires more electrons to complete its octet. Hence GaH3 is electron deficient.

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