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Q.

How many of the following statements are correct? 

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a

A dirty green ppt forms when ferrous sulphate reacts with an excess of NaOH

b

Hydration energy of Cu+ is more than Cu2+

c

The process of purification of nickel is:

Ni(impure) +4CO450470KNi(CO)4330350KNi(pure) +4CO 

d

Green solution forms when cooper sulphate reacts with Iron.

answer is A, C, D.

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Detailed Solution

Dirty green ppt of Fe(OH)2 forms when FeSO4 reacts with an excess of NaOH.

FeSO4+2NaOHFe(OH)2Dirty green ppt+Na2SO4

Impure nickel first treated with a poisonous gas, CO and forms a volatile compound, Ni(CO)4. This compound further heated to obtain pure nickel.

Fe+CuSO4Blue colorFeSO4Green color+Cu

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