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Q.

How many orbitals are there in the third shell n3?

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Detailed Solution

Understanding Atomic Shells and Orbitals

1. Principal Quantum Number (n)

  • The principal quantum number, n, indicates the shell or main energy level of an electron in an atom.
  • The value of n can be any positive integer (1, 2, 3, ...).
  • n=3 refers to the third shell.

2. Subshells and Quantum Numbers

Each shell is divided into subshells, labeled as s, p, d, f, etc., determined by the azimuthal quantum number (l):

  • For a given n, possible values of l range from 0 to n-1.
  • For n=3:
    • l = 0 → 3s subshell
    • l = 1 → 3p subshell
    • l = 2 → 3d subshell

3. Orbitals in Each Subshell

Each subshell contains a specific number of orbitals, determined by the magnetic quantum number (ml):

  • Number of orbitals in each subshell = 2l + 1
Subshelll valueNumber of orbitalsOrbital labels
3s013s
3p133p-1, 3p0, 3p1
3d253d-2, 3d-1, 3d0, 3d1, 3d2

4. Total Number of Orbitals in the n=3 Shell

Add up the orbitals in each subshell:

  • 3s: 1 orbital
  • 3p: 3 orbitals
  • 3d: 5 orbitals

Total orbitals in third shell (n=3):

1 (3s) + 3 (3p) + 5 (3d) = 9 orbitals

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