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Q.

Hybridisation of the underline atom changes in:  

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a

AlH3  changesto AlH4

b

H2O  changes to H3O+

c

inall cases  

d

NH3  changes to NH4+

answer is A.

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Detailed Solution

 Hybridisation =12 No. of electrons  in valence  shell of atom +  No.of monovalent  atoms around it  charge on  cation +  charge on  anion 

 (a) ForAlH3  Hybridisation of Al atom =12[3+30+0] =3=sp2  For AlH4  Hybridisation of Al atom =12[3+40+1] =4=sp3
 (b) ForH2O  Hybridisation of O atom  =12[6+20+0]=4=sp3  For H3O+, Hybridisation of O atom  =12[6+31+0]=4=sp3
 (c) For NH3  Hybridisation of N atom  =12[5+30+0]=4=sp3  For NH4+,Hybridisation of N atom  =12[5+41+0]=4=sp3  Thus hybridisation changes only in option (a). 

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