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Q.

Hydration energies of  Li+ and Clare - 499 and - 382 k.J mole1 .If lattice energy of LiCl is +840 k.Jmole1 , heat of solution of LiCl  is 

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a

– 41 kJ mole -1

b

– 1621 kJ mole1

c

+41 kJ mole1      

d

–12.22 kJ  mole1

answer is D.

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Detailed Solution

Heat of Solution = Lattice energy + Hydration energy
= + 840 - 499 – 382 = -41kJ mole-1

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Hydration energies of  Li+ and Cl−are - 499 and - 382 k.J mole−1 .If lattice energy of LiCl is +840 k.Jmole−1 , heat of solution of LiCl  is