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Q.

Hydration enthalpy of Li+ is lesser than that of Be+2. Lithium is the best reducing agent among alkali metals in aqueous solutions. The best reducing agent among second group elements in aqueous solution is

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a

Be

b

Ca

c

Ba

d

Sr

answer is C.

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Detailed Solution

Hydration enthalpy(exothermic) of Be+2 is high but at the same time the sum of IP1, and IP2(endothermic) is also very high;

the process, Ms+ΔHsubMg+ΔHIE1M+g+ΔHIE2M+2g+ΔHHydM+2aq is not so feasible in the case of beryllium in aqueous solution;

The reducing power of Be < Mg < Ca < Sr < Ba  Ra

 

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