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Q.

Hydrazine, a component of rocket fuel, undergoes combustion to yield  N2 and  H2O.
N2H4(l)+O2(g)N2(g)+2H2O(l) 
What is the change in internal energy for above reaction of N2H4 (in kJ/mole)?
Given: Reaction                                                                            ΔH(kJ)

2NH3(g)+3N2O(g)4N2(g)+3H2O(l)                      1011  kJ

N2O(g)+3H2(g)N2H4(l)+H2O(l)                              317  kJ
4NH3(g)+O2(g)2N2H4(l)+2H2O(l)                       286kJ

H2(g)+12O2(g)H2O(l)                                                  285  kJ

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a

-622.75

b

None of these 

c

-620.5 

d

1167.5

answer is A.

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Detailed Solution

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 0.5NH3+0.75N2ON2(g)+0.75H2O(l)----(i) 0.75N2H4+0.75H2O0.75N2O(g)+2.25H2(g)---(ii) 0.25N2H4+0.25H2O0.5NH3+18O2(g)-----(iii) 2.25H2+1.125O22.25H2O(g)------(iv) 14(i)34(ii)18(iii)+94(iv)  =620.5

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