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Q.

Hydrogen atom in its ground state is excited by a radiation of wavelength 97.26 nm. The longest wavelength it emits is

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a

1250 nm

b

1875 nm

c

1400 nm

d

2050 nm

answer is C.

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Detailed Solution

ΔE=hcλ=6.626×1034Js3×108ms197.26×109m=2.0438×1018J

Also ΔE=2.18×1018J1121n22

Hence 1n22=1ΔE2.18×1018J=12.0436×10182.18×1018=10.9374n2=1/(10.9374)4

The transition n2=4n1=3 will emit the longest wavelength. Hence

ΔE=2.18×1018J132142=1.06×1019Jλ=hcΔE=6.626×1034Js3×108ms11.06×1019J=1.875×106m=1875nm

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