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Q.

Hydrogen gas is liberated when aluminium is treated with
A) Air
B) Dilute HCl (or) H2SO4
C) NaOH (or) KOH
D) conc. HNO3

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a

all the above

b

only A, B and C

c

only B, C and D

d

only B and C

answer is D.

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Detailed Solution

detailed_solution_thumbnail

Aluminium dissolves in dilute HCl and liberates dihydrogen

2Als+6HClaq2Alaq3++6Claq-+3H2g

However, concentrated nitric acid renders aluminium passive by forming a protective oxide layer on the surface.
Aluminium also reacts with aqueous alkali and liberates dihydrogen.

2Als+2NaOHaq+6H2Ol2Na+AlOH4aq-sodium tetrahydroxoaluminate(III)+3H2g

Aluminium forms a very thin oxide layer on the surface which protects the metal from further attack.

2Als+3O2g2Al2O3s

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