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Q.

Hydrogen is collected over water at 22° C and a barometer reading of 7 40 mm.Hg. If 300 mL of hydrogen is collected, which expression will give the volume of dry hydrogen at the same temperature and pressure?

Compound                                      Vapour Pressure at 22° C

H2O                                                20 mm Hg

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a

300mL×740mmHg20mmHg740mmHg

b

300mL×740mmHg+20mmHg740mmHg

c

300mL×740mmHg740mmHg20mmHg

d

300mL×740mmHg740mmHg+20mmHg

answer is A.

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Detailed Solution

Volume of dry hydrogen at the same temperature and pressure;

V=300×700200740

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