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Q.

Hydrogen-like ion has the wavelength difference between the first lines of Balmer and lyman series equal to 33.4nm. The atomic number of that ion equal to RH=1.1×107m1

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a

2

b

3

c

4

d

5

answer is A.

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Detailed Solution

Given,

λBλL=334 nm

Atomic number, Z = ?

Use the formula,1λ=RH1n121n22×Z2

Where,  

l wave length of radiation

RH = Rydberg's constant

n2 = Higher energy level = 3

n1 = lower energy level = 2

1λ1=R122-132Z2

λ1=365RZ2

1λ2=R112-122

λ2=43RZ2

Δλ=λ1-λ2=365RHZ2-43RHZ2

334=365-43×1RH×1Z2

Z2=5.86×912334

=16

Z=4

 

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