Q.

Hydrolysis of phenyl isocyanide forms

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a

benzoic acid

b

none of these

c

formic acid

d

acetic acid

answer is B.

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Detailed Solution

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The hydrolysis of phenyl isocyanide (C₆H₅NC) in the presence of acidic or basic conditions forms formic acid (HCOOH) and aniline (C₆H₅NH₂) as products.

Explanation:

  • Phenyl isocyanide undergoes hydrolysis where the isocyanide group (-NC) breaks down.
  • During this reaction:
    • The -NC group is converted to a formic acid (-COOH) group.
    • The phenyl group remains attached to the nitrogen, forming aniline.

Reaction:

C₆H₅NC + 2H₂O → C₆H₅NH₂ (aniline) + HCOOH (formic acid)

Correct Answer:

(b) Formic acid

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