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Q.

Hydrolysis of phosphodiester groups is the backbone of DNA, has $Δ G^{\circ} = - 5.5 k c a l / m o l$ at $27^{\circ} C$ . Approximate equilibrium constant for the hydrolysis reaction is:

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a

$10^{10}$

b

$10^{9}$

c

$10$

d

$10^{4}$

answer is B.

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Detailed Solution

Here, we know that,

$Δ G^{\circ} = - 2.303 R T \log_{10} K$

$- 5.5 \times 10^{3} = - 2.303 \times 8 \times 300 \times \log_{10} k$

$K = 10^{4}$

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