Q.

I = ClCH2COOH, II = formic acid, III = CHCl2COOH, IV = C6H5COOH.  Correct acidic strength order is 

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a

III > II > I > IV

b

III > I > IV > II

c

IV > III > I > II 

d

III > I > II > IV

answer is A.

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Detailed Solution

EWG increase the acidic strength of aliphatic carboxylic acids by-I effect.

I effect of CF3>NO2>CN>F>Cl>Br>I>Ph

EDG decrease the acidic strength of aliphatic carboxylic acids by +I effect

Alkyl groups shows +I effect;

+I effect increase with increase in chain length and bulkiness of alkyl group.

 Acidic strength of O2NCH2COOH>NCCH2COOH>FCH2COOH>CH3COOH>RCH2COOH

Inductive effect weakens as the distance increases.

Presence of EWG at α-position makes acetic acid (or) propionic more acidic than formic acid.

Let an EWG is present at β-position of acetic acid (or) propionic acid. It is less acidic than formic acid. 

Thus Cl2CHCOOH>ClCH2COOH>HCOOH>C6H5COOH

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