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Q.

I) benzene 1,2-diol II) benzene 1,3-diol
III) benzene 1,4-diol IV) Phenol

The increasing order of boiling points of above mentioned Phenol(s) is

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a

$I < I I < I I I < I V$

b

$I < I I < I V < I I I$

c

$I V < I < I I < I I I$

d

$I V < I I < I < I I I$

answer is C.

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Detailed Solution

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Reason-I: Intermolecular H-bonding and intramolecular H-bonding
Reason-II: Molecular weight

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