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Q.

(i) Draw structures of the following derivatives

(a) Cyanohydrin of cyclobutanone

(b) Hemiacetal of ethanal

(ii) Write a major product(s) in the following

(a) CH3-CH=CH-CH2-CN (II) H3O+(I) DIBAL-H

(b) CH3-CH2-OHCrO3

(iii) How can you distinguish between propanal and propanone?

OR

(i) Identify compound ‘A’ . Its molecular formula is C2H4O2 and gives brisk effervescence with NaHCO3.
(ii) Identify the major products X andY of reaction
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(iii) Identify C of the following sequence of reactions
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Detailed Solution

(i)

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(ii) (a) Product is CH3-CH=CH-CH2-CHO

       (b) Product is CH3-CH2-CHO

(iii) Propanal and propanone can be distinguished by using Tollen’s test. Propanal being an aldehyde reduces Tollen’s reagent to shining silver mirror and propanone being a ketone does not.

OR

(a) CS2+2Cl2AlCl3CCl4+S2Cl2

(b) C6H5NH2+CHCl3+KOH+C6H5NC+3KCl+3H2O(c) C2H5Br+AgCNC2H5NC+AgBr

(d) CCl3CHO+NaOHCHCl3+HCOONa

(e) 2C2H5Br+2ZnC2H52Zn+ZnBr2

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