(I)1, 2-dihydroxy benzene
(II) 1, 3-dihydroxy benzene
(III) 1, 4-dihydroxy benzene
(IV) Hydroxy benzene
The increasing order of boiling points of above mentioned alcohols is

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IV<II<I<III

I<II<III<IV

I<II<IV<III

IV<I<II<III

answer is C.

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Detailed Solution

1, 4-dihydroxy benzene shows the highest boiling point among given compounds because it forms strong intermolecular hydrogen bonds (It does not form intermolecular H-bonding.)

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