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Q.

Ice-water mass ratio is maintained as 1 : 1 in a given system containing water in equilibrium with ice at constant pressure. If CP( ice )=CP( water )=4.18J mol−1K−1  molar heat capacity of such a system is :

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a

zero

b

4.182JK−1mol−1

c

75.48JK−1mol−1

d

infinity

answer is B.

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Detailed Solution

Heat capacity can be given as,

C=dQdT

We have given that,

dT=0

Thus, the heat capacity,

C=dQ0
⇒C=∞

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