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Q.

Identify A and B in the following reaction, CH3CH3BCH3COOHACH3CH2OH
 

 AB
1HI + Red PLiAlH4
2Ni/LiAlH4
3LiA/H4 HI + Red P
4Pd-BaSO4Zn + HCl

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a

1

b

2

c

3

d

4

answer is C.

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Detailed Solution

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CH3CH3B CH3COOH → A CH3CH2OH

Options

OptionAB
1HI + red PLiAlH4
2Ni / ΔLiAlH4
3LiAlH4HI + red P
4Pd–BaSO4Zn + HCl

Answer

Option (3)

A = LiAlH4, B = HI + red P

LiAlH4 reduces carboxylic acids to primary alcohols:
CH3COOH → CH3CH2OH

HI (with red P, heated) reduces the –COOH group to the corresponding alkane (loss of the carboxyl carbon):
CH3COOH → CH3CH3

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