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Q.

Identify correct statement(s) from the following given options : 

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a

The expression for % ionisation of a dilute solution of a monoacidic weak base in aqueous solution is  1001+10(pKbpOH)

b

An acidic indicator Hln (colourless) will be visible only when its ionised form (pink in colour) is 25 % by mole or more of total indicator in a solution. Suppose Hln  (pKa=9.0) is added to a solution having pH = 9.6 then mole % of ionised form of HIn in solution is 90%, (Take log 2 = 0.3) 

c

Molar solubility of  AgCl(KSP=1012) in  0.2 M MgCl2 aqueous solution is 2.5×1012M.

d

If equal volumes of following solutions are mixed, then the pH of resulting solution will be average value of pH of two given solutions at  25°C. 
Solution I :  pH=5(CH3COOH) (aq) & Solution-II :  pH = 9 (NH3(aq)),
Given :  [Ka(CH3COOH)=Kb(NH3(aq))]

answer is A, B, D.

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Detailed Solution

Ans. ( A,B,D )

A)  Question Image
(B)  [H+] from CH3COOH=105[OH]  from NH3=105 Complete neutralisation takes place Final  
Question Image

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