Identify correct statements :
(A) Primary amines do not give diazonium salts when treated with NaNO₂ in acidc condition.
(B) Aliphatic and aromatic primary amines on heating with CHCl₃ and ethanolic KOH form carbylamines.
(C) Secondary and tertiary amines also give carbylamine test.
(D) Benzenesulfonyl chloride is known as Hinsberg's reagent.
(E) Tertiary amines reacts with benzenesulfonyl chloride very easily.
Choose the correct answer from the options given below :

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(B) and (D) only

(A) and (B) only

(D) and (E) only

(B) and (C) only

answer is A.

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Detailed Solution

(A) Question Image
(B)
(C) Only primary amine gives carbyl amine test
(D) Ph–SO₂Cl $\to$ Hinsberg reagent Benzene sulphonyl chloride
(E) Tertiary amine do not react with Ph–SO₂Cl

So correct options are (B) and (D) only

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