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Q.

Identify the correct options regarding $I_{2} C l_{6}$ ?

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a

It contains two three centre – four electron bonds

b

It is $s p^{3} d^{2}$ hybridization of Iodine

c

It contains three centre – two electron bonds

d

It is dimer of $I C l_{3}$

answer is A, B, C.

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Detailed Solution

Dimerization of $I C l_{3}$ through donation of non-bonding electron pair of ‘Cl’ into vacant orbital of ‘I’ of another $I C l_{3}$ unit results in formation of $I_{2} C l_{6}$ . As per molecular orbital theory, $I_{2} C l_{6}$ has two three Centre – four electron bonds.

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