Q.

Identify the correct order of boiling points of the following compounds

a)  CH3CH2CH2CH2OH

b) CH3CH2CH2CHO

c) CH3CH2CH2COOH

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a

c > a > b

b

a > c > b

c

a > b > c

d

c > b > a

answer is B.

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Detailed Solution

Carboxylic acid has highest boiling point because of extensive H-bonding, after that alcohol has more boiling point than aldehyde because of strong H-bonding. Therefore, the correct trend is c>a>b.

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