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Q.

Identify the correct order of reactivity of the following towards the nucleophilic substitution
1) 

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2) 

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3) 

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4) 

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a

1> 3 > 2 > 4 

b

3 > 1 > 4 > 2

c

4 > 3 > 2 > 1

d

2 > 3 > 4 > 1

answer is A.

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Detailed Solution

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The presence of nitro group at ortho- and para-positions withdraws the electron density from the benzene ring and thus facilitates the attack of the nucleophile on haloarene.

 

 

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