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Q.

Identify the correct statement among the following.
a) Solubility of alkaline earth metal hydrides in water increases down the group
b) Thermal decomposition of (NH4)2 BeF4 gives BeF2
c) In the vapour phase BeCl2 tends to form dimer
d) Hydride of calcium is also called hydrolith
 

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a

 a, b, c & d
 

b

a, c & d only

c

 b, c & d only
 

d

a, b & c only
 

answer is A.

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Detailed Solution

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Down the group the lattice energies of alkali metal hydroxides decrease due to the increase in atomic size. Further down the group ionic character of these hydroxide increases due to increase in electropositive character. So the solubilities increase.

(NH4)2BeF4⟶2NH4F+BeF2

In the vapour phase BeCl2 tends to form a chloro-bridged dimer which dissociates into the linear monomer at high temperatures of the order of 1200 K.

Hydrolith is basically a salt-like binary compound having the chemical formula CaH2.

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