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Q.

Identify the correct statement for B2H6 from those given below.

(A)  In B2H6, all BH bonds are equivalent. 

(B)  In B2H6 there are four 3-centre-2-electron bonds. 

(C) B2H6 is a Lewis acid. 

(D) B2H6 can be synthesized form both BF3 and NaBH4  

(E) B2H6 is a planar molecule. 

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a

(C) and (E) only

b

(B), (C) and (E) only

c

(A) and (E) only

d

(C) and (D) only

answer is C.

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Detailed Solution

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(A) (B) Two 3 center– 2 – electron bonds

 (C) B2H6 is edeficient species   (E) B2H6 is non - Planar molecule   (D) BF3+LiAlH42B2H6+3LiF+3AlF3 NaBH4+I2B2H6+2NaI+H2

 

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