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Q.

Identify the correct statement(s) among the following 

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a

MOT successfully explains the paramagnetic nature of O2 molecle

b

N2 molecule is paramagnetic with two unpaired electrons

c

The process O2(g)  O2+(g)  results in increased OO  bond energy

d

NO+ ion is diamagnetic

answer is A, C, D.

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Detailed Solution

(A) According to MOT,  O2 molecule possesses two unpaired electrons in antibonding M.O.s Hence it is paramagnetic.
(B)  N2  : σ1s2,σ*1s2,σ2s2,σ*2s2,π2px2,π2py2,σ2pz2  . So its B.O is ‘3’ and diamagnetic (Hence false)
(C) Bond energy   bond order. Bond order in O2  is 2, while in O2+  , the bond order is 2.5
(D) NO has odd electron. It is lost in the formation of  NO+   
 

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