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Q.

Identify the correct statement(s) in the light of quantitative estimation of aqueous ferrous ions by using acidified permanganate or acidified dichromate solution, under conditions of concentration of all species as 1 M. 

MnO4(aq)+8H+(aq)+5eMn2+(aq)+4H2O(l);Eo=1.51  V

Cr2O72(aq)+14H+(aq)+6e2Cr3+(aq)+7H2O(l);Eo=1.38V

Fe3+(aq)+eFe2+(aq);Eo=0.77V

Cl2(g)+2e2Cl(aq);Eo=1.40  V

 

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a

MnO4  can be used in aqueous HCl

b

Cr2O72can be used in aqueous HCl

c

 MnO4 can be used in aqueous  H2SO4

d

 Cr2O72can be used in aqueous  H2SO4

answer is B, D, C.

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Permanganate oxidises Chloride ion

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