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Frenkel defect appears in AgI, ZnS and AgBr.

Zinc blend structure is obtained when Zn⁺² occupies half tetrahedral sites

Ferrimagnetism is in the alignment of magnetic moments

but not in

In antifluorite structure cations are arranged in CCP while anions occupy all the tetrahedral voids.

answer is A.

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Detailed Solution

1.Frenkel defect appears in AgI, ZnS and AgBr.

2.Zinc blend structure is obtained when Zn⁺² occupies half tetrahedral sites

3.Ferrimagnetism is in the alignment of magnetic moments

but not in

4.In antifluorite structure, anions form CCP structure while the tetrahedral sites are occupied by the cations. Each cation at tetrahedral void is surrounded by 4 oxide anions and the oxide anions are surrounded by 8 cations, each. Hence, the coordination number of cation is 4 and coordination number of anion is 8.

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