Q.

Identify the correct statements 

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a

The solution formed by mixing equal volumes of 0.1 M urea and 0.1 M   glucose will have the same osmotic pressure.

b

For association of a solute in a solution, I > 1

c

0.1MK4Fe(CN)6 and 0.1MAl2SO43 are isotonic solutions 

d

The ratio of van’t   Hoff factors for 0.2 M glucose and 0.1 M sucrose is 2:1

answer is A.

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Detailed Solution

Osmolic pressure ,p = i × C × S × T

Urea & glucose  name i = 1 as they are non –electrolytes

For association i<

Glucose & Sucrose are also non-electrolysis & hance , i=1

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