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Identify the correct statements among the Following
A) m.pt order: p-dichlorobenzene > o-dichloro benzene
B) B.pt : order: o-dichlorobenzene >p-dichloro benzene
C) Reactivity order for nucleophilic substitution:

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only A

only B

A&B only

A,B,C

answer is D.

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Detailed Solution

Molecular packing is the main criteria for determining melting point order. P -Dichlorobenzene is symmetrical and easily fits into a crystal lattice

The boiling point of ortho dichlorobenzene is greater than the boiling point of meta and para dichlorobenzene due to its greater polar nature . The boiling point order is ortho > meta > para dichlorobenzene

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