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Q.

Identify the correct statements from the following
I) In [CoCl(NH3)5]2+, the Lewis acid is Co3+
II) An example for heteroleptic complex is [Co(NH3)6]3+
III) The hybridisation of Mn in [MnBr4]2– is dsp2
IV) In[Ni(CO)4], the metal-carbon bond possesses σ and π character

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a

ii, iii

b

i, ii, iii, iv

c

i, iv

d

i, iii, iv

answer is B.

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Detailed Solution

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  •  In [CoCl(NH3)5]2+, the Lewis acid is Co3+, it accept electron pair from NH3
  • In[Ni(CO)4], the metal-carbon bond possesses σ and π character due to synergic bond.
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