Identify the correct statements.

I)  ${\mathrm{CH}}_3^{+}$is more stable than ${\mathrm{CH}}_3-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$

II) is more stable than ${\mathrm{CH}}_3-{\mathrm{CH}}_2-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$

III)${\mathrm{CH}}_2=\mathrm{CH}-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$ is more stable than ${\mathrm{CH}}_3={\mathrm{CH}}_2-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$

IV) t - butyl carbo cation is more stable than $\mathrm{C}{\mathrm{H}}_3\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$

I) Ethyl carbo cation has 3 $\mathrm{\alpha }$ hydrogens and methyl carbocation has no $\mathrm{\alpha }$ hydrogens. Hence ethyl carbocation has 3 hyper conjugative structures and is more stable than methyl carbocation.

II) Dimethyl carbocation (2^o carbocation) has 6 $\mathrm{\alpha }$ hydrogens and has 6 hyper conjugative structures. On the other hand, n-propyl carbocation has 2 $\mathrm{\alpha }$ hydrogens and has 2 hyper conjugative structures. Hence, Dimethyl carbocation is more stable than n-propyl carbocation.

III) ${\mathrm{CH}}_2=\mathrm{CH}-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$ is allyl carbocation and is involved in resonance while ${\mathrm{CH}}_3={\mathrm{CH}}_2-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$ does not show resonance. Hence ${\mathrm{CH}}_2=\mathrm{CH}-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$ is more stable than ${\mathrm{CH}}_3={\mathrm{CH}}_2-\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$.

IV) t-butyl carbocation has 9 $\mathrm{\alpha }$ hydrogens while $\mathrm{C}{\mathrm{H}}_3\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$ has 3 $\mathrm{\alpha }$ hydrogens. Hence, t-butyl carbocation is more stable than $\mathrm{C}{\mathrm{H}}_3\stackrel{\oplus }{\mathrm{C}}{\mathrm{H}}_2$.