Q.

Identify the elements X and Y using the ionisation energy values given below:

Ionisation energy (kJ/mol)

 1st 2nd
X4954563
731 145

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a

X=Mg;   Y=Na

b

X=F ; Y=Mg

c

X=Na ; Y=Mg

d

X=Mg;  Y=F

answer is A.

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Detailed Solution

Due to 2p6, noble gas electronic configuration, the second ionisation enthalpy of Na is very high. That's why has large difference between IE1 and IE2 of Mg+ is 2p6, 3 s1.

After the loss of one electron, Mg2+ will be formed with a noble gas electronic configuration. That's why there is less difference between IE1and IE2.

Hence, the required option is A.

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