Q.

Identify the formal charges on the marked nitrogen in the following structure :

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a

N1=1,    N2=0,    N3=+1,    N4=+1

b

N1=0,    N2=+1,    N3=1,    N4=1

c

N1=0,    N2=0,    N3=+1,    N4=2

d

N1=+1,    N2=0,    N3=+1,    N4=1

answer is A.

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Detailed Solution

The formal charges on the marked nitrogen in the following structure is,N1=0,    N2=0,    N3=+1,    N4=2

An atom's electric charge within a molecule is known as its formal charge (FC).

Formal charge = Total number of valence electrons-(1/2) total number of shared electrons in bonds- total number of unbound electrons 

The distribution of electric charge within a molecule can be estimated using formal charge.

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Identify the formal charges on the marked nitrogen in the following structure :