Q.

Identify the homoleptic complex(es) that is/are low spin.
(A) Fe(CN)5NO2-
(B) CoF63
(C) Fe(CN)64
(D) CoNH363+
(E) CrH2O62+
Choose the correct answer from the options given below :

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a

(B) and (E) only

b

(A) and (C) only

c

(C) only

d

(C) and (D) only

answer is C.

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Detailed Solution

(A) Fe(CN)5NO2 Heteroleptic, Fe+2, 3d6,t2g6eg0,d2sp3Low spin (3d series + SFL)
(B) CoF63 Homoleptic, sp3d2, High spin, Co+3,3d6 (3 d series +WFL)
(C) Fe(CN)64 Homoleptic
Fe+2,3d6,d2sp3,t2g6eg0 Low spin
(3 d series +SFL)
(D) CoNH36+3 Homoleptic, Co+33d6,d2sp3,t2g6eg0, Low spin (3d series +SFL )
(E) CrH2O6+2 Homoleptic
Cr+23d4,d2sp3, High spin t2g3eg1
(3d series + WFL)

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