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Q.

Identify the incorrect statement:

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a

The S - S - S bond angles in $S_{8}$ and $S_{6}$ rings are the same

b

Rhombic and monoclinic sulphur have $S_{8}$ molecule

c

$S_{2}$ is paramagnetic like oxygen

d

$S_{8}$ ring has a crown shape.

answer is A.

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Detailed Solution

a The S–S–S bond angles in the S8 and S6 rings are the same. Explanation:The S6 molecule has a chair-form hexagon ring with the same bond length as that in S8 but with some what smaller bond angles i.e. bond lengths are same but bond angles are different.

The bond angle in $S_{8}$ and $S_{6}$ are different. $S_{8}$ adopts a puckered ring or "Crown" structure. $S_{6}$ adopts a chair form.

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