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Identify the incorrect statement from the following.

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The shapes of d_xy, d_yz, and d_zx orbitals are similar to each other; and are similar to each other.

All the five 5d orbitals are different in size when compared to the respective 4d orbitals.

All the five 4d orbitals have shapes similar to the respective 3d orbitals.

In an atom, all the five 3d orbitals are equal in energy in free state

answer is C.

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Detailed Solution

The shape of $d_{xy}, d_{yz}, d_{zx} = dumbell$
$d_{x^{2} - y^{2}} = dumbell$
$d_{z^{2}} =$ dumbell shape with a doughnut – shaped electron cloud in the center.

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